Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures.

نویسندگان

  • Keren Zhang
  • Gregory B Fahs
  • Motohiro Aiba
  • Robert B Moore
  • Timothy E Long
چکیده

RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-Tg soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.

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عنوان ژورنال:
  • Chemical communications

دوره 50 65  شماره 

صفحات  -

تاریخ انتشار 2014